Main Article Content

Abstract

Abstract. Dragon fruit peel is a material that is abundant and cheap. The material has been used as an adsorbent in the biosorption process for the removal of metal ions of Cd(II) from wastewater. Biosorption of Cd(II) ion by dragon fruit peel was done on the variation of contact time, pH and concentration. The concentration of metal ions Cd(II) before and after adsorption was determined using Atomic Absorption Spectrophotometer (AAS). Results showed that the optimum time was 20 minutes and the optimum pH was 5. Adsorption capacity was studied by both isotherm adsorptions of Langmuir and Freundlich. Results showed that the biosorption of Cd(II) ion using dragon fruit peel full filled the isotherm Langmuir model with the biosorption capacity (Qo) of 36,50 mg/g. The functional group involved in metal ion biosorption of Cd(II) by the peel of dragon fruit is a hydroxyl group (-OH).

Keywords

Biosorption Cd(II) adsorption isotherm dragonfruitpeel AAS

Article Details

How to Cite
A.M, T., La Nafie, N., & Taba, P. (2015). BIOSORPTION OF Cd(II) ION BY DRAGON FRUIT PEEL (Hylocereus polyrhizus). Jurnal Akta Kimia Indonesia (Indonesia Chimica Acta), 8(1), 18-30. https://doi.org/10.20956/ica.v8i1.2478

References

  1. Achmad, R., 2004, Kimia Lingkungan, ANDI Yogyakarta, Yogyakarta.
  2. Ahmad, A., Rafatullal, M., Sulaiman, O., Ibrahim, M.H., Chii, Y.Y., and Siddique, B.M., 2009, Removal of Cu(II) and Pb(II) ions from aqueous solutions by adsorption on sawdust of Meranti wood, Desalination, 250, 300-310.
  3. Bailey, S.E., Olin, T.J., Bricka, R.M., and Adrian, D.D., 1999, A Review of Potentially Low-Cost Sorbents for Heavy Metals, Water Res., 33(11), 2469-2479.
  4. Fatoni, A., Hindryawati, N., and Sari, N., 2010, Pengaruh pH Terhadap Adsorpsi Ion Logam Kadmium(II) oleh Adsorben Jerami Padi, J. Kimia Mulawarman, 7(5), 59-61.
  5. Hawari, A.H., and Mulligan, C.N., 2006, Biosorption of Lead(II), Cadmium(II), Copper(II), and Nickel(II) by Anaerobic Granular
  6. Biomass, Bioresour. Technol.,97, 692-700.
  7. Jethva, H.O., 2015, FTIR Spectroscopic and XRD Analysis of Gel-Grown, Cadmium Levo- Tartrate Crystals, IJAR, 1(4), 1-3.
  8. La Nafie, N., Zakir, M., and Karoma, M.J., 2012, Pemanfaatan Serbuk Kayu Meranti Merah (Shorea parvifolia) Sebagat Biosorben Ion Logam Cd(II), Indo. Chim. Acta, 5(2), 32-40.
  9. Mallampati, R., 2013, Biomimetic Synthesis Of Hybrid Materials For Potential Applications, A Thesis unpublished, Department Of Chemistry National University Of Singapore, Singapore.
  10. Nailufar, A.A., 2010, Biosorpsi Ion Cd(II) oleh Ampas Tahu, Skripsi tidak diterbitkan, Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Hasanuddin.
  11. Pabiban, D., 2009, Biosorpsi Ion Cd(II) oleh Ampas Sagu, Skripsi tidak diterbitkan, Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Hasanuddin.
  12. Priyantha, N., Lim, L.B.L., Dahri, M.K.,and Tennakoon, D.T.B., 2013, Dragon Fruit Skin As a Potential Low-Cost Biosorbent For The Removal of Manganese(II) Ions, JASES, 8(3), 179-188.
  13. Saikaew, M., and Kaewsarn, P., 2010, Durian Peels As Biosorbent For Removal Of Cadmium Ions From Aqueous Solution, J. Environ. Res., 32(1), 17-30.
  14. Umar, M. R., and Liong, S., 2014, Efektifitas Serbuk Biji Kelor Moringa Oleifera Lamk.Dalam Menurunkan Kadar Kadmium (Cd) Pada Air, J. Alam dan Lingkungan, 5(8), 37-42.
  15. Viera, R.H.S.F., and Volesky, B., 2000, Biosorption; a solution to pollution, Int. Microbiol, 3, 17-24.
  16. Volesky, B., 2001, Detoxificiation of metal-bearing eluents. Biosorption for the next centry, Hydrometallurgy, 59(2), 203–216.
  17. Widihati, I.A.G., Ratnayani, O., and Angelina, Y., 2010, Karakterisasi Keasaman dan Luas Permukaan Tempurung Kelapa Hijau (Cocos Nucifera) dan Pemanfaatannya Sebagai Biosorben Ion Cd2+, J. Kimia, 4(1), 7-14.
  18. Umar, M. R., and Liong, S., 2014, Efektifitas Serbuk Biji Kelor Moringa Oleifera Lamk.Dalam Menurunkan Kadar Kadmium (Cd) Pada Air, J. Alam dan Lingkungan, 5(8), 37-42.
  19. Viera, R.H.S.F., and Volesky, B., 2000, Biosorption; a solution to pollution, Int. Microbiol, 3, 17-24.
  20. Volesky, B., 2001, Detoxificiation of metal-bearing effluents. Biosorption for the next centry, Hydrometallurgy, 59(2), 203–216.
  21. Widihati, I.A.G., Ratnayani, O., and Angelina, Y., 2010, Karakterisasi Keasaman dan Luas Permukaan Tempurung Kelapa Hijau (Cocos Nucifera) dan Pemanfaatannya Sebagai Biosorben Ion Cd2+, J. Kimia, 4(1),7-14.