DETERMINATION AND DEGRADATION PYRENE FROM PAOTERE PORT SEDIMENTS WITH OXIDIZER KMnO4

Rachma Surya Masnawan, Nursiah La Nafie, Adiba Arief

Abstract


Paotere port is one of port in Makassar which functions as a stopover place of ships, also serves as fish market and fishermen settlements. Various activities of transportation, commerce and households occurred in the Paotere port area can be a source of pollution of pyrene compounds to the surrounding environment. Pyrene compounds that accumulate and can not be degrade will impact the environment and marine life. Determination pyrene in sediment from Paotere Port have been carried out using GC-MS by sonication using dichloromethane as solvent. Result show that there was no PAH in sediment of the three sampling stations. Pyrene compound chemically degradation was conducted by sonication for 1 hour using an oxidant KMnO4 concentration of  0.05 M, 0.07 M and 0.1 M. Results show that KMnO4 as oxidizing agent could to degrade the whole pyrene with concentration of 87,8554 ng/g in sediment.

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References


Yahya, M., 2013, Rekayasa Lingkungan Pelabuhan Pendaratan Ikan (PPI) di Pelabuhan Paotere, Temu Ilmiah IPLBI, 1-6.

Osman, W. W., Amin, S., dan Musdaliana, 2013, Pola Penggunaan Lahan Pada Kawasan Pesisir Kota Makassar, Group Teknik Arsitektur, 7; 1-11.

Rahim, I. R., dan Ali, S. H., 2014, Studi Pengelolaan Sampah Pelabuhan Soekarno-Hatta Makassar, Simposium Nasional RAPI XIII, ISSN 1412-9612; 71-77.

Mochtar, K., 1992, Perlindungan dan Pelertarian Lingkungan Laut Dilihat dari Sudut Hukum Internasional, Regional, dan Nasional, Sinar Grafika dan Pusat Studi Wawasan Nusantara, Jakarta.

Ahmad, F., 2012, Kandungan Senyawa Polisiklik Aromatik Hidrokarbon (PAH) di Teluk Jakarta, Ilmu Kelautan, 17 (4); 199-208.

Environmental Protection Agency (EPA), 1995, Toxicological Profile For Polycyclic Aromatic Hydrocarbons, Department of Health and Human Service, Atlanta.

Krivobok, S., Kuony, S., Meyer, C., Louwagie, M., Willison, J. C., and Jouanneau, Y., 2003, Identification of Pyrene-induced Proteins in Mycrobacterium sp. strain 6PY1; Evidence for Two Ring-Hydroxylating Dioxygenases. J.Bacteriol. 185 (13); 3828-2841.

Sarbini, K., 2012, Biodegradasi Piren Menggunakan Bacillus Subtilis C19. Fakultas Tekik Program Studi Teknologi Bioproses departemen Teknik Kimia. Universitas Indonesia. Depok.

Rauscher, L., 2012, Using Slow-Realease Permanganate to Remediate PAH Contaminated Water (Thesis), Faculty of The Environmental Studies Program, University of Nebraska, Lincoln.

Choplin, L., Lazaroiu, Gh., Store, C., and Bogdan I., 2011, Pottasium Permanganate Oxidation Treatment For The Polycyclic Aromatic Hydrocarbons Contaminated Soils, Journal of Sustainable Energy, 2 (3); 30-35.

Silva, C.K. O., Aguiar, L. G., Ciriaco, M. F., Vianna, M. M. G., R., Nascimento, C. A. O., Chiavone-Filho, O., Pereira, C. G., and Foletto, E. L., 2014, Remediation of Solid Matrix Containing Antracene and Phenanthrene By Permanganate Oxidatint, Global NEST Journal, 16 (2); 393-401.

Huling, S. G., and Pivetz, B. E., Tanpa Tahun, In-Situ Chemical Oxidation, EPA US, Cincinnati.

Ismail, H. E., 2016, Degradasi Senyawa Piren dengan Menggunakan Isolat Bakteri Yang Berasal dari Perairan Pelabuhan Paotere, Thesis tidak diterbitkan, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Hasanuddin, Makassar.

Simanjuntak, M., 2009, Hubungan Faktor Lingkungan Kimia, Fisika Terhadap Distribusi Plankton Di Perairan Belitung Timur, Bangka Belitung, J. Fish Sci., (1); 31-45.

Gassa, M. S., 2010, Pengembangan SOP Analisis Polisiklik Aromatik Hidrokarbon, Pustaka Ramadhan, Bandung.

Sanusi, H. S., 2006, Kimia Laut; Proses Fisik Kimia dan Interaksinya Terhadap Lingkungan. Departemen Ilmu dan Teknologi Kelautan, Fakultas Perikanan dan Ilmu Kelautan, Institut Pertanian Bogor.

Agency for Toxic Substances and Disease Registry (ATSDR), Tanpa Tahun, Toxicological Profile for Phenol, Departement of Health and Human Service, Atlanta GA; US.

Pawar, R. M., The Effect of Soil pH on Degradation of Polycyclic Aromatic Hydrocarbons (PAHs) (Thesis), University of Hertfordshire, United Kingdom.


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