Pengaruh Penambahan Ion Mg2+ Terhadap Kandungan Lipid Fitoplankton Chlorella vulgaris Sebagai Bahan Baku Pembuatan Biodiesel dengan Metode Ultrasonik

Authors

  • Alfani M Datu Department of Chemistry, Hasanuddin University
  • Indah Raya Department of Chemistry, Hasanuddin University
  • Muhammad Zakir Department of Chemistry, Hasanuddin University

Abstract

An investigation on the effect   of Mg2+     on its lipid content from phytoplankton Chlorella vulgaris as a raw material for producing biodiesel by ultrasonic method has been carried out. The  results  showed  that  Mg2+   is  good  as  a  nutrient  for  phytoplankton.    The  optimum concentration was 0.4 ppm. Total of dry biomass was 32.7902 grams. Lipid was extracted  by ultrasonic method using ethanol 95% as solvent. Biodiesels were syntesized in two steps namely esterification by methanol solvent and H2SO4 as catalyst, folowed by transesterification by using methanol solvent with KOH as a catalyst. Total of biodiesel made was 11.5727 grams and the yield  was  35.29%. The result  of  biodiesel  characterised  in term of  physical  and  chemical characteristics including:   density, viscosity, free fatty acid, saponification value, and iodine value, respectively.   Result of the analysis showed that biodiesel characteristics have fulfilled standard the American  Society for Testing and  Materials  (ASTM D6751), except  value of density and Free Fatty Acid.

References

Astuti, J.T., Sriwuryandri, L., dan Sembiring, T., 2011, Pengaruh Penambahan Mg2+ Terhadap Produktifitas Komposisi Asam Lemak Microalgae Scenedesmus Sebagai Bahan Biodiesel, Jurnal Riset Industri, 5 (3): 265-274.

EL-Metwally, A.E., Abdalla, F.E., El-Saady, A.M., Safina, S.A., and EI-Sawy S.S., 2010, Response of Wheat to Magnesium and Copper Foliar Feeding under Sandy Soil Condition, J. Am. Sci., 6 (12): 818-823.

Irdoni, H.S., 2012, Pengaruh Kecepatan Pengadukan pada Proses Pembuatan Biodiesel dari Minyak Jarak Pagar (Jatropha curcas l) dengan menggunakan Katalis Abu Tandan Sawit, (Online), (http://repository.unri.ac.id/bitstream/123456789/506/1/irdoni1.PDF, diakses 8 Mei 2012).

Li, H., Pordesimo, L., and Weiss, J., 2004, High intensity ultrasound-assisted extraction of oil from soybeans, Food Res. Int., 37: 731–738.

Li, Y., Horsman, M., Lan, C.Q., and Dubois-Calero M., 2008, Biofuels from Microalgae,

Biotechnol. Prog., 24 (4): 815-820.

Liu ZY, Wang GC, and Zhou BC. 2008. Effect of iron on growth and lipid accumulation in

Chlorella vulgaris. Bioresour. Technol., 99 (11): 4717–4722.

Mata, T.M., Martins, A.A., and Caetano, N.S., 2010, Microalgae for Biodiesel Production and other Aplications: A Revew, Renew. and Sustainable Energy Revews, 14 (1): 217-232.

McNamara III, W.B., Didenko, Y.T., and Suslick, K.S., 1999, Sonoluminescence temperatures during multi-bubble cavitation, Nature, 401:772-775.

Panangan, A.T., Yoandini H., dan Gultom J.U., 2011, Analisis Kualitatif dan Kuantitatif

Asam Lemak Tak JenuhOmega-3 dari Minyak Ikan Patin (Pangasius pangasius)

dengan Metoda Kromatografi Gas, Jurnal Penelitian Sains, 14 (4): 38-42.

Rachamniah, O., Setyarini, R.D., dan Maulida, L., 2010, Pemilihan Metode Ekstraksi Minyak Alga dari Chlorella sp. dan Prediksinya Sebagai Biodiesel, Seminar Teknik Kimia Soehadi Reksowardojo, Jurusan Teknik Kimia, Fakultas Teknologi Industri, Institut Teknologi Sepuluh November, Surabaya.

Stavarache, C., Vinatoru, M., and Maeda, Y., 2007, Aspects of Ultrasonically Assisted

Transesterification of Various Vegetable Oils WITH methanol, Ultrason. Sonochem.,

: 380-386.

Sudarmadji, S., 1989, Analisa Bahan Makanan dan Pertanian, Liberty Yogyakarta, Yogyakarta.

Supardan, M.D., 2011, Penggunaan Ultrasonik Untuk Transesterifikasi Minyak Goreng

Bekas, Jurnal Rekayasa Kimia dan Lingkungan, 8 (1): 11-16.

Surya, D., 2006, Optimalisasi Proses Sintesis Biodiesel dari Minyak Biji Jarak Pagar (Jathropa curcas L.) Dengan Menggunakan Katalis KOH Berdasarkan variasi suhu, skripsi tidak diterbitkan, Jurusan Kimia FMIPA Universitas Hasanuddin, Makassar.

Taba, P., Zakir, M., Kasim, A.H., dan Fauziah, S., 2011, Penuntun Praktikum Kimia Fisika, Laboratorium Kimia Fisika Jurusan Kimia Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas Hasanuddin, Makassar.

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Published

2013-10-30