Produksi Biodiesel dari Lipid Fitoplankton Nannochloropsis sp. Melalui Metode Ultrasonik
Abstract
A research on production of biodiesel from lipid of phytoplankton Nannochloropsis sp. through ultrasonic extraction method has been done. In this research, we carried out a series of phytoplankton culture to determine the optimum time of growth and biodiesel synthesis process from phytoplankton lipids. Process of biodiesel synthesis consists of two steps, i.e isolation of phytoplankton lipids and biodiesel synthesis from that lipids. Oil isolation process was carried out by ultrasonic extraction method using ethanol 96 % while biodiesel synthesis was carried out by transesterification reaction using methanol and KOH catalyst under sonication. Percentage rendement of weight per biomass Nannochloropsis sp. is 48,33 %. Characterization of biodiesel was carried out in terms of physical properties: density, viscosity, and chemical properties: FFA content, saponification value, and iodine value. The result showed that analysis characterization biodiesel phytoplankton Nannochloropsis sp. that biodiesel from that species phytoplankton generally fullfilled the American Society for Testing and Materials (ASTM D6751) standard, except density value was 0,8151 g.cm-3, viscosity value was 1,15 cSt, and FFA content was 0,5381 %, to be used as fuel.References
Azam, M. M., Warris, A., dan Nahar, N. M., 2005, Prospects and Potential of Fatty Acid Metyl Esters of Some Non-Traditional Seed Oils of Use Biodiesel in India, Biomass and Bioenergy, India. Aziz, I., Nurbayati, S., dan Ulum, B., 2011, Pembuatan Produk Biodiesel dari Minyak Goreng Bekas dengan Cara Esterifikasi dan Transesterifikasi, Valensi, 2:3, 443-448.
Crabbe, E., Hipolito, C. N. N., Kobayashi, G., Sonomoto, K., dan Ishizaki, A., 2001, Biodiesel Production From Crude Palm Oil and Evaluation of Butanol Extraction and Fuel Properties, Process Biochem., 37, 65-71.
Knothe, G., 2005, Dependence of Biodiesel Fuel Properties on The Structure of Fatty Acid
Alkyl Esters, Fuel Proc. Technol., 86, 1059-1070.
Nirwana, I.HS., 2012, Pengaruh Kecepatan Pengadukan Pada Proses Pembuatan Biodiesel dari Minyak Jarak Pagar (Jatropha curca L) dengan Menggunakan Katalis Abu Tandan Sawit, Lembaga Penelitian, Universitas Riau, Riau.
Mata, T. M., Martins, A. A., Caetano, N. S., 2010, Microalgae for Biodiesel Production and
Other Applications: A Review, Renew. Sustainable Energy Rev., 14, 217-232.
Rachmaniah, O., Setyarini, R. D., dan Maulida, L., 2010, Pemilihan Metode Ekstraksi Minyak Alga dari Chlorella sp. dan Prediksinya Sebagai Biodiesel, Seminar Teknik Kimia Soehadi Reksowardojo, Jurusan Teknik Kimia, Fakultas Teknologi Industri, Institut Teknologi Sepuluh November, Surabaya.
Seafdec, 1985, Prawn Hatchery Design and Operational, Aquaculture Extention ManualNo.9, Aquaculture Department, Tigbauan, Ilolo, Philippines.
Supardan, M. D., 2011, Penggunaan Ultrasonik untik Transesterifikasi Minyak Goreng
Bekas, Jurnal Reakayasa Kimia dan Lingkungan, 8:1, 11-16.
Suslick, K. S., Didenko, Y., Fang, M. M., Hyeon, T., Kolbeck, K. J., McNamara III, W. B., Mdleleni, M. M., dan Wong, M., 1999, Acoustic Cavitation and Its Chemical Consequences, Phil Trans. R. Soc. Lond. A., 357, 335-353.
Thompson, L. H., dan Doraiswamy, L. K., 1999, Sonochemist ry: Science and
Engineering,Ind. Eng. Chem. Res., 38, 1215-1249.
Triantoro, K., 2008, Alga Mikro Scenedesmus sp. Sebagai Salah Satu Alternatif Bahan Baku Biodiesel di Indonesia, Karya Tulis Ilmiah, Fakultas Matematika dan IlmuPengetahuan Alam Universitas Negeri Yogyakarta, Yogyakarta.
Yosta, E. R., Harimurti, D. W., dan Rachmaniah O., 2009, Studi Pendahuluan: Ekstraksi Minyak Alga dari Spirulina sp. Sebagai Wacana Baru Bahan Baku Alternatif Pada Proses Pembuatan Biodiesel, Institut Teknologi Sepuluh November,Surabaya.