Article Sidebar

Submitted
Sep 16, 2017
Accepted
Sep 16, 2017
Published
Jun 1, 2015
Download
PDF
Statistic
Read Counter : 259 Download : 6

Downloads

Download data is not yet available.

Main Article Content

Abstract

Nickel is one of the heavy metals which is very dangerous because it is carcinogenic and can cause a variety of acute and chronic diseases. Biosorption is one alternative method for the removal of heavy metals from the environment using a biomaterial called biosorbent. Biosorption of Ni(II) ion using cacao fruit peel (Theobroma cacao) with variation of contact time, pH and concentration has been investigated. The concentration of Ni(II) ion before and after adsorption was determined by Atomic Absorption Spectrophotometer (AAS). The result showed that cacao fruit peel (Theobroma cacao) was able to adsorb Ni(II) ion and the optimum biosorption occured at a contact time of 10 minutes and at a pH of 5. Langmuir and Freundlich isotherm models were used to study the adsorption isotherm. Biosorption of Ni(II) ion by cacao fruit peel (Theobroma cacao) fulfilled the Langmuir isotherm with a biosorption capacity of 0,21 mmol/g. The functional groups involved in the  biosorption of Ni(II) ion by cacao fruit peel (Theobroma cacao) are –OH and N-H.

Keywords

Biosorption adsorption isothermal Ni(II) cacao fruit peel AAS

Article Details

How to Cite
M, M., La Nafie, N., & Taba, P. (2015). UTILIZATION OF CACAO FRUIT PEEL (Theobroma cacao) AS A BIOSORBENT OF Ni(II) IONS METAL. Jurnal Akta Kimia Indonesia (Indonesia Chimica Acta), 8(1), 31-41. https://doi.org/10.20956/ica.v8i1.2479
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX

References

  1. Ahmad, A., Rafatullah, M., Sulaiman O., Ibrahim, M.H., Chii, Y.Y., dan Siddique, B.M., 2009, Removal Of Cu(Ii) And Pb(II) Ions from Aqueus Solutions by Adsorption on Sawdust of Meranti Wood, Desal, 250, 300-
  3. Alluri, H.K., Ronda, S.R., Settaluri, V.S., Singh, Bondili, J.S., Suryanarayan, V., and Venkateshwar, P., 2007, Biosorption: An Eco- friendly Alternative for Heavy Metal Removal, Afr. J. Biotechnol., 6(25): 2924-2931.
  4. Amaliah, R., La Nafie, N., and Fauziah, S., 2012, Pemanfaatan Karang sebagai Biosorben Ion Logam Ni(II), Mar. Chim. Acta., 13(1): 36-
  6. Aslam, M.Z., Shahid, N.R., dan Feroze, N., 2010, Ni(II) Removal By Biosorption Using Ficus Religiosa (Peepal) Leaves, J. Chil. Chem. Soc.,
  7. (1): 81-84.
  8. El-Sayed, G.O., Dessouki H.A., and Ibrahim S.S., 2010, Biosorption of Ni (II) and Cd (II) Ions From Aqueous Solutions Onto Rice Straw, Chem. Sci. J., 1-11.
  9. Ina A.T., Yulianti, L.I.M., dan Pranata, F.S., 2013, Pemanfaatan Pektin Kulit Buah Jeruk Siam (Citrus nobilis var. microcarpa) Sebagai Adsorben Logam Tembaga (Cu), Skripsi tidak diterbitkan Fakultas Teknobiologi Universitas Atma Jaya, Yogyakarta.
  10. Isnaini, P., Zein, R., dan Munaf, E., 2013, Penyerapan Ion Cd (II) dan Zn
  11. (II) dalam Air Limbah Menggunakan Kulit Jengkol (Pithecellobium jiringa
  12. Prain), J. Kim. Unand, 2(3): 20-30.
  13. Kusuma, I.D.G.D.P., Wiratini N.M., dan Wiratma I.G.L., 2014, Isotermal Adsorpsi Cu2+ oleh Biomassa Rumput Laut, e-Journal Kim. Visvitalis Univ. Pen. Ganesha, 2(1): 1-10.
  14. Masitoh, Y.F., dan Sianita, M.M., 2013, Pemanfaatan Arang Aktif Kulit buah Coklat (Theobroma cacao L.) sebagai Biosorben logam berat Cd (II) dalam Pelarut Air, J.Chem., 1(1): 23-
  16. Onundi, Y. B., Mamun, A. A., Al- Khatib, M. F., and Ahmed, Y. M.,
  17. , Adsorption of copper, nickel and lead ions from synthetic semiconductor industrial wastewater by palm shell activated carbon, Int. J. Environ. Sci. Tech., 7 (4): 751-758.
  18. Rozaini, C.A., Jain, K., Tan, K.W., Tan, L.S., Azraa, A., and Tong, K.S.,
  19. , Optimization of Nickel and Copper Ions Removal by Modified Mangrove Barks, Int. J. Chem. Eng. Appl., 1(1): 84-89.
  20. Sembodo, B.S.T., 2006, Model Kinetika Langmuir untuk AdsorpsiTimbal pada Abu Sekam Padi, Ekuilibrium, 5(1): 28-33.
  21. Setyawan, F.L., Darjito, dan Khunur, M.M., 2013, Pengaruh pH dan Lama Waktu pada Adsorspi Ca2+ Menggunakan Adsorben Kitin Terfosforilasi dari Limbah Cangkang Bekicot (Achatina Fulica), Kim. Student J., 1(2): 201-207.
  22. Sulistyawati, 2008, Modifikasi Tongkol Jagung Sebagai Adsorben Logam Berat Pb(II), Skripsi tidak diterbitkan, Departemen Kimia Fakultas Matematika dan Ilmu Pengetahuan Alam Institut Pertanian Bogor, Bogor.
  23. Triyani, N.P., Suhartana, dan Sriatun, 2013, Sintesis dan Karakterisasi Kompleks Ni(II)-EDTA dan Ni(II)- Sulfanilamid, Chem Info, 1(1): 354-